Jean-Marc Triscone awarded a honorary doctorate

by the Norwegian University of Science and Technology (NTNU)

Read more

next Q-MAC meetings in 2018:

3rd Q-MAC symposium in Venice, May 22-25, 2018.

Next regular meeting in Paris, November 27-28, 2018.

Read more

Publication Detail / Abstract

J. Ruppen, J. Teyssier, O. E. Peil, S. Catalano, M. Gibert, J. Mravlje, J.-M. Triscone, A. Georges, D. van der Marel

Optical spectroscopy and the nature of the insulating state of rare-earth nickelates

published in Physical Review B on October 27, 2015
> Full text via publisher
Using a combination of spectroscopic ellipsometry and DC transport measurements, we determine the temperature dependence of the optical conductivity of NdNiO3 and SmNiO3 films. The optical spectra show the appearance of a characteristic two-peak structure in the near-infrared when the material passes from the metal to the insulator phase. Dynamical mean-field theory calculations confirm this two-peak structure and allow us to identify these spectral changes and the associated changes in the electronic structure. We demonstrate that the insulating phase in these compounds and the associated characteristic two-peak structure are due to the combined effect of bond disproportionation and Mott physics associated with half of the disproportionated sites. We also provide insights into the structure of excited states above the gap.
< Back